TY - JOUR AU - Nóvoa, Luis AU - Trulli, Laura AU - Parra, Alejandro AU - Tortosa, Mariola PY - 2020/11/25 Y2 - 2024/03/29 TI - Copper, Boron and Vinyl Epoxides: from 1,4-Diols to Cyclopropylboronates JF - CHIMIA JA - Chimia VL - 74 IS - 11 SE - Scientific Articles DO - 10.2533/chimia.2020.852 UR - https://www.chimia.ch/chimia/article/view/2020_852 SP - 852 AB - Herein we describe the reactivity found between vinyl epoxides and catalytically generated copper-boryl complexes. By tuning the substituents of the alkene and/or the reaction conditions, 1,4-diols, allylic alcohols or cyclopropylboronates can be prepared. The stereochemical information of the vinyl epoxide is transferred to the products with high levels of stereocontrol. ER -