TY - JOUR AU - Lacôte, Emmanuel PY - 2016/02/24 Y2 - 2024/03/29 TI - Polymer-containing Organo-Polyoxometalate: Towards New Catalytic Object JF - CHIMIA JA - Chimia VL - 70 IS - 1-2 SE - Scientific Articles DO - 10.2533/chimia.2016.29 UR - https://www.chimia.ch/chimia/article/view/2016_029 SP - 29 AB - Polyoxometalates (POMs) are early transition metal oxide clusters, which form a diverse family of compounds with highly tunable shapes, sizes, charges, etc. Generating hybrid structures is an attractive path to increase the structural diversity of POMs. The present article is a personal account that retraces how we inserted polyoxometallic platforms onto polymeric chains. We focused on two main families of functionalized organo-POMs: the organotin-substituted Dawson polyoxotunstates ?1 and ?2-[P2W17O61(SnR)]7– and the Dawson vanadotungstates [P2V3W15O59{(OCH2)2-C(Et)NHC(=O)R}]5–. Herein we discuss how the connection of POMs to polymers affects the self-assembly of the polymers and the catalytic properties of the polyoxometalates. ER -