TY - JOUR AU - Fässler, Thomas F. AU - Hoffmann, Rudolf PY - 1998/04/29 Y2 - 2024/03/28 TI - Clusters of the Heavier Elements of Main Groups 14–16: A Novel Synthetic Route for Polyanions in Molten Crown Ether JF - CHIMIA JA - Chimia VL - 52 IS - 4 SE - Scientific Articles DO - 10.2533/chimia.1998.158 UR - https://www.chimia.ch/chimia/article/view/1998_158 SP - 158 AB - <p>A novel procedure allows the synthesis of homoatomic polyanions directly from the elements E (E = Sn, As, Sb, Te) in molten A/18-crown-6 as reaction medium (A = K, Rb) at temperatures between 40 and 80° [1]. The reactions are carried out by adding E to mixtures of A and 18-crown-6 that proved to form stable melts under these conditions. Further work off using ethylenediamine or DMF as solvent yielded single crystals of the following compounds: [K(18-crown-6)]<sub>4</sub>Sn<sub>9</sub> (<strong>1</strong>), [K(18-crown-6)]<sub>3</sub>KSn<sub>9</sub>·en (<strong>2</strong>), [K(18-crown-6)]<sub>3</sub>As<sub>7</sub> (<strong>3</strong>), [K([2.2.2]crypt)]<sub>2</sub>[K(18-crown-6)]Sb<sub>7</sub>·0.5en (<strong>4</strong>), [Rb(18-crown-6)]<sub>3</sub>Sb<sub>7</sub> (<strong>5</strong>), [K(18-crown-6)]<sub>2</sub>Te<sub>4</sub> (<strong>6</strong>), and [K(18-crown-6)]<sub>2</sub>Te<sub>4</sub>·en (<strong>7</strong>). In all compounds short contacts between the Zintl ions and A-atoms are observed. The influence of cation-anion interactions on the structure of these anions is discussed.</p> ER -