A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
Keywords:Bioinspired model, Diiron complex, Hydrogenase, Mesoionic carbene, Proton reduction
AbstractA novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(?-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.
How to Cite
A. Mele, S. Bertini, M. Albrecht, C. Elleouet, F. Y. Pétillon, P. Schollhammer, Chimia 2020, 74, 499, DOI: 10.2533/chimia.2020.499.
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.