Reaktivität von Koordinationsverbindungen XVI :  Hydrolyse von Vanadium(IV)-Chelaten

Authors

  • Th. Kaden Institut für anorganische Chemie der Universität Basel
  • S. Fallab Institut für anorganische Chemie der Universität Basel

DOI:

https://doi.org/10.2533/chimia.1966.51

Abstract

Various Vanadium(IV)-chelates have been studied in their tendency to hydrolyse and the potentiometrically determined pK-values are discussed. The structure of a partially hydrolysed complex with picolinic acid is thoroughly investigated. Spectrophotometric evidence leads to the conclusion that OH- is in trans-position to the VO-group.

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Published

1966-02-28

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Section

Kurze Mitteilungen