Zur Cu2+-katalysierten Reaktion zwischen Wasserstoffperoxid und Hydrazin bzw. Hydroxylamin

Authors

  • Hans Erlenmeyer Institut für Anorganische Chemie der Universität Basel (Schweiz)
  • Claus Flierl Institut für Anorganische Chemie der Universität Basel (Schweiz)
  • Helmut Sigel Institut für Anorganische Chemie der Universität Basel (Schweiz)

DOI:

https://doi.org/10.2533/chimia.1968.433

Abstract

The catalysis by Cu2+ and by the Cu2+-2,2'-bipyridyl-1:1- complex of the peroxydative reaction between H2O2 and NH2NH2, and H2O2 and NH2OH, respectively were characterized. The stability constants of the complexes Cu2+–NH2NH2, Cu2+–NH2OH, Cu2+-bipyridyl-NH2NH2 and Cu2+-bipyridyl-NH2OH were calculated. The degree of formation of these complexes is compared with the pH at which the reactions start.

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Published

1968-11-30

Issue

Vol. 22 No. 11 (1968): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1968 Hans Erlenmeyer

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
H. Erlenmeyer, C. Flierl, H. Sigel, Chimia 1968, 22, 433, DOI: 10.2533/chimia.1968.433.