Discogene Monothioscyllitol-Derivate

Authors

  • Bernd Kohne Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Klaus Praefcke Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Werner Stephan Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12

DOI:

https://doi.org/10.2533/chimia.1986.14

Abstract

Two derivatives (3 and 4) of the hitherto unknown 1-deoxy- 1-mercapto-scyllo-inositol (monothioscyllitol), a sulfur analogue of the naturally occurring scyllo-inositol, have been prepared by nucleophilic substitution reaction from a hexaester of myo-inositol (2). They are the first thermotropic discotic liquid crystalline compounds with an alicyclic saturated «core» and a non-centrosymmetric structure exhibiting strong dipole moments in benzene solution and wide mesophase ranges.

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Published

1986-01-31

Issue

Vol. 40 No. 1 (1986): Forschung/Research

Section

Articles

License

Copyright (c) 1986 Bernd Kohne

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
B. Kohne, K. Praefcke, W. Stephan, Chimia 1986, 40, 14, DOI: 10.2533/chimia.1986.14.