Thermal Decomposition of Vicinal Dinitroalkanes

Authors

  • Katharina Fritzsche Institut für Organische Chemie und Biochemie Albert-Ludwigs-Universität Albertstrasse 21, D-7800 Freiburg i.Br. (Bundesrepublik Deutschland)
  • Hans-Dieter Beckhaus Institut für Organische Chemie und Biochemie Albert-Ludwigs-Universität Albertstrasse 21, D-7800 Freiburg i.Br. (Bundesrepublik Deutschland)
  • Christoph Rüchardt Institut für Organische Chemie und Biochemie Albert-Ludwigs-Universität Albertstrasse 21, D-7800 Freiburg i.Br. (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1988.106_2

Abstract

Three sym-tetraalkyl-dinitroethanes 1-3 have been decomposed in solution at 180 to 215 °C. The alkylated 1,3-butadienes 10,12, and 13 are formed by elemination of HNO2. No products could be observed, which were generated by homolytic cleavage of the central C–C bond. Thus the dimers of tertiary α-nitroalkyl radicals (9) do not cleave into 9 by heating. 

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Published

1988-03-31

Issue

Vol. 42 No. 3 (1988): Forschung/Research

Section

Articles

License

Copyright (c) 1988 Katharina Fritzsche

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
K. Fritzsche, H.-D. Beckhaus, C. Rüchardt, Chimia 1988, 42, 106, DOI: 10.2533/chimia.1988.106_2.