Reactions of Trienals Catalyzed by Chiral Ruthenium Lewis Acids

Authors

  • Sirinporn Thamapipol
  • E. Peter Kündig

DOI:

https://doi.org/10.2533/chimia.2011.268

PMID:

28982407

Keywords:

Asymmetric imda reaction, Chiral catalyst, Diels-alder, Lewis acid, Ruthenium

Abstract

Chiral single-point binding ruthenium Lewis acid catalysts [Ru(acetone)((S,S)-BIPHOP-F)(Cp)][SbF6] ((S,S)-1a) and [Ru(acetone)((S,S)-BIPHOP-F)(indenyl)][SbF6] ((S,S)-1b) efficiently catalyze intramolecular Diels-Alder (IMDA) reactions of trienals under mild conditions to afford the endo cycloaddition products as the major products in good yields with high diastereo- and enantioselectivities.

CHIMIA Vol. 65 No. 4 (2011): Laureates: Awards and Honors SCS Fall Meeting

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Published

2011-04-27

Issue

Vol. 65 No. 4 (2011): Laureates: Awards and Honors SCS Fall Meeting 2010

Section

Scientific Articles

License

Copyright (c) 2011 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
S. Thamapipol, E. Peter Kündig, Chimia 2011, 65, 268, DOI: 10.2533/chimia.2011.268.