Free-radical Carbo-functionalization of Olefins Using Sulfonyl Derivatives
Keywords:Allylation, Azidation, Carbonylation, β-fragmentation, Oximation, Radical addition, Sulfones
AbstractThis review provides an overview of the recent progress made in the area of free-radical additions across the ?-system of olefins, with a focus on the role of sulfonyl derivatives as one of the reaction partners in multicomponent processes. The mechanism and utility in organic synthesis of carbo-alkenylation, alkynylation, oximation and azidation of olefins are thus discussed and illustrated with some applications in total synthesis of natural products.
How to Cite
B. Ovadia, F. Robert, Y. Landais, Chimia 2016, 70, 34, DOI: 10.2533/chimia.2016.34.
Copyright (c) 2016 Swiss Chemical Society
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