Photolyse und Acidolyse von 2,3-Diaza-bicyclo[3,2,0]hepten-Derivaten

Authors

  • H. Prinzbach Institut de Chimie Organique, Université de Lausanne.
  • H.-D. Martin Chemisches Laboratorium der Universität Freiburg im Breisgau (Deutschland).

DOI:

https://doi.org/10.2533/chimia.1969.37

Abstract

The bridgehead substituted 2,3-diaza-bicyclo[3.2.0]heptene-derivatives 7 and 21 are synthesized. The photolysis to the bicyclo[2.1.0]pentane 6a and the acid catalyzed isomerization to the dihydrodiazepines 12a and 22 are described. The activation energy for the transformation 6a → 9a has been determined to be roughly 29 kcal/mole.

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Published

1969-01-31

Issue

Vol. 23 No. 1 (1969): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1969 H. Prinzbach

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
H. Prinzbach, H.-D. Martin, Chimia 1969, 23, 37, DOI: 10.2533/chimia.1969.37.