Isomérisation et oxydation du trans-phyténal

Authors

  • Y. Bessière-Chrétien Laboratoire de Chimie de l’Ecole Normale Supérieure 24, rue Lhomond, F-75 Paris 5
  • J.P. Marion Laboratoire de Chimie de l’Ecole Normale Supérieure 24, rue Lhomond, F-75 Paris 5

DOI:

https://doi.org/10.2533/chimia.1970.306

Abstract

t-Phytenal is isomerised and oxidised in solution under various conditions. In CCl4, rapid isomerisation to the cis form occurs. Oxidation proceeds through a Baeyer-Villiger mechanism, followed by epoxidation and rearrangement of the epoxyformiate to the aldehydo-formiate. Specific oxidations with p-nitroperbenzoic acid and H2O2/NaOH yielded reference products which enabled determination of this reaction mechanism from t-phytenal to its last oxidation step, phytone.

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Published

1970-08-31

Issue

Vol. 24 No. 8 (1970): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1970 Y. Bessière-Chrétien

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Y. Bessière-Chrétien, J. Marion, Chimia 1970, 24, 306, DOI: 10.2533/chimia.1970.306.