Palladiumkomplexe mit porphinoidem Ligandsystem

Authors

  • Peter Geisser Institut für organische Chemie der Universität Bern
  • Peter Schmid Institut für organische Chemie der Universität Bern
  • Rolf Scheffold Institut für organische Chemie der Universität Bern

DOI:

https://doi.org/10.2533/chimia.1980.279

Abstract

In the presence of palladium(II) salts the bicyclic amidine 1 forms diazaporphinpalladium complexes by cyclocondensation. Depending on the reaction conditions the 1,11-dimethoxy complex 2, the 1-methoxy complex 3 or the annulene complex 4 are obtained. 2, 3 and 4 can be interconverted by reversible addition and elimination reactions.

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Published

1980-06-30

Issue

Vol. 34 No. 6 (1980): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1980 Peter Geisser

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
P. Geisser, P. Schmid, R. Scheffold, Chimia 1980, 34, 279, DOI: 10.2533/chimia.1980.279.