On the Physical Meaning of Parameters E0 and β in Dubinin's Theory

Authors

  • Fritz Stoeckli Chemistry Department of the University, Av. de Bellevaux 51, CH-2000 Neuchatel, Switzerland
  • Daniel Morel Chemistry Department of the University, Av. de Bellevaux 51, CH-2000 Neuchatel, Switzerland

DOI:

https://doi.org/10.2533/chimia.1980.502

Abstract

A comparative study of limiting adsorption energies in microporous carbons and on graphitized carbon blacks shows that their difference is proportional to the quantity βE0 which appears in Dubinin’s theory. It follows that the characteristic energy E0 must be related to an average pore size, as found empirically. The affinity coefficient β, on the other hand, can be regarded as a shifting factor, directly related to the ratio of gas-solid adsorption potentials.

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Published

1980-12-31

Issue

Vol. 34 No. 12 (1980): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1980 Fritz Stoeckli

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
F. Stoeckli, D. Morel, Chimia 1980, 34, 502, DOI: 10.2533/chimia.1980.502.