Kristallstruktur eines 2-Dimethylamino-3,3-dimethyl-4(3H)-pyridons

Authors

  • Jost H. Bieri Organisch-chemisches Institut der Universität Zürich
  • Roland Prewo Organisch-chemisches Institut der Universität Zürich
  • Heinz Heimgartner Organisch-chemisches Institut der Universität Zürich

DOI:

https://doi.org/10.2533/chimia.1982.7

Abstract

3-Dimethylamino-2,2-dimethyl-2H-azirine (1) reacts with alkyl phenyl substituted cyclopropenones 2 in benzene at 130 °C to give a mixture of the two isomeric 4(3H)-pyridones 3 and 4, resulting from a nucleophilic attack at C(2) and C(1) of the cyclopropenone. In acetonitrile the isomer 3 is formed exclusively. The crystal structure of the 5-isopropyl derivative 3a (R = CH(CH3)2) has been established by X-ray structure determination.

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Published

1982-01-31

Issue

Vol. 36 No. 1 (1982): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1982 Jost H. Bieri

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
J. H. Bieri, R. Prewo, H. Heimgartner, Chimia 1982, 36, 7, DOI: 10.2533/chimia.1982.7.