Tetracarbonyl (η5-cyclopentadienyl) vanadium Complexes with R3E Substituents (E = Si, Ge, Sn) at the Cp-Ring

Authors

  • Adreas Duch Institut für Anorganische und Angewandte Chemie Universität Hamburg Martin-Luther-King-Platz 6, D-2000 Hamburg 13 (Bundesrepublik Deutschland)
  • Martin Hoch Institut für Anorganische und Angewandte Chemie Universität Hamburg Martin-Luther-King-Platz 6, D-2000 Hamburg 13 (Bundesrepublik Deutschland)
  • Dieter Rehder Institut für Anorganische und Angewandte Chemie Universität Hamburg Martin-Luther-King-Platz 6, D-2000 Hamburg 13 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1988.179

Abstract

The preparation and spectral properties (IR, 1H- and 51V-NMR, MS) of the complexes [(η5-R3EC5H4)V(CO)4], R3E = Me3Si, Et3Ge, Et3Sn and n-Bu3Sn, are described. These compounds are obtained by direct reaction from V(CO)6 and R3EC5H5. The complexes [R3EV(CO)6] are formed as by-products in the case of E = Sn and Ge. With Ph3PbC5H5, the only metalated complex is [Ph3PbV(CO)6].

Downloads

Published

1988-05-31

Issue

Vol. 42 No. 5 (1988): Forschung/Research

Section

Articles

License

Copyright (c) 1988 Adreas Duch

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
A. Duch, M. Hoch, D. Rehder, Chimia 1988, 42, 179, DOI: 10.2533/chimia.1988.179.