Synthese des Chlorselenonitren-Molybdänkomplexes [Cl4Mo=N=SeCl]2

Authors

  • Jörg Adel Fachbereich Chemie der Universität Marburg Hans Meerwein-Strasse, D-3550 Marburg 1 (Bundesrepublik Deutschland)
  • Kurt Dehnicke Fachbereich Chemie der Universität Marburg Hans Meerwein-Strasse, D-3550 Marburg 1 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1988.413

Abstract

[MoCl4(NSeCl)]2 has been prepared by the reaction of Se4N4 with molybdenum pentachloride in boiling dichloromethane, forming a black, diamagnetic, moisture-sensitive crystal powder, which is characterized by its IR spectrum. The reaction of [MoCl4(NSeCl)]2 with tetraphenylphosphonium chloride leads to the well-known nitrido complex Ph4P[MoCl4N].

Downloads

Published

1988-12-31

Issue

Vol. 42 No. 12 (1988): Forschung/Research

Section

Articles

License

Copyright (c) 1988 Jörg Adel

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
J. Adel, K. Dehnicke, Chimia 1988, 42, 413, DOI: 10.2533/chimia.1988.413.