A Cationic Compound of Ru25⊕ Containing a Coordinated PF4O⊖ Ion

Authors

  • F. Albert Cotton Department of Chemistry and Laboratory for Molecular Structure and Bonding Texas A&M University College Station, TX 77843 (USA)
  • Marek Matusz Department of Chemistry and Laboratory for Molecular Structure and Bonding Texas A&M University College Station, TX 77843 (USA)

DOI:

https://doi.org/10.2533/chimia.1989.167

Abstract

The compound Ru2(PhNNNPh)4 was oxidized in CH2Cl2 with AgPF6. From a CH2Cl2/(C2H5)2O solution left to evaporate in air for one month blue-green crystals of Ru2(PhNNNPh)4OPF4, in which the PF4O⊖ ion is coordinated to one Ru atom (Ru–O: 220(1) pm), were obtained. Other principal distances are: Ru–Ru 238.5(2) pm, P–O 145.5(11) pm, P–F 159(1) pm. Angles in the PF4O⊖ ion are: O–P–F 111.6(4)°, F–P–F (cis) 82.2(6)°, F–P–F (trans) 136.7(6)°.

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Published

1989-06-30

Issue

Vol. 43 No. 6 (1989): Forschung/Research

Section

Articles

License

Copyright (c) 1989 F. Albert Cotton

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
F. A. Cotton, M. Matusz, Chimia 1989, 43, 167, DOI: 10.2533/chimia.1989.167.