Luminescence of Tris(2,2'-bipyridine)ruthenium(II) Incorporated at Moderate Temperature in Sol-Gel Glasses and Various Low-Melting Glasses

Authors

  • Renata Reisfeld Department of Inorganic Chemistry The Hebrew University 91904 Jerusalem (Israel)
  • David Brusilovsky Department of Inorganic Chemistry The Hebrew University 91904 Jerusalem (Israel)
  • Marek Eyal Department of Inorganic Chemistry The Hebrew University 91904 Jerusalem (Israel)
  • Christian K. Jørgensen Département de Chimie minérale, analytique et appliquée Université de Genève Quai Ernest Ansermet 30 CH 1211 Genève 4

DOI:

https://doi.org/10.2533/chimia.1989.385

Abstract

The luminescent and higher excited states of [Ru(bpy)3]2⊕ are critically discussed, and compared with new measurements in sol-gel glasses, a lead tin fluorophosphate glass (made at 280 °C), boric acid (230 °C), and polyvinylalcohol film (90 °C). The effects that decrease the luminescence yield to below 0.2 at 25 °C are considered.

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Published

1989-12-31

How to Cite

[1]
R. Reisfeld, D. Brusilovsky, M. Eyal, C. K. Jørgensen, Chimia 1989, 43, 385, DOI: 10.2533/chimia.1989.385.