tert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon–Nitrogen Bond Forming Reactions
Keywords:Amination, Tert-butanesulfinamide, Chiral nucleophiles
AbstractThe use of tert-butanesulfinamides as nitrogen nucleophiles in carbon–nitrogen bond forming reactions is reviewed. This field has grown in the shadow of the general interest in N-tert-butanesulfinyl imines for asymmetric synthesis and occupies now an important place in its own right in the chemistry of the chiral amine reagent tert-butanesulfinamide. This article provides an overview of the area and emphasizes recent contributions wherein the tert-butanesulfinamides act as chiral auxiliaries or perform as nitrogen donors in metal-catalyzed amination reactions.
How to Cite
J. R. Hernandez, F. Chemla, F. Ferreira, O. Jackowski, J. Oble, A. Perez-Luna, G. Poli, Chimia 2016, 70, 84, DOI: 10.2533/chimia.2016.84.
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