Photoelectrochemical Cells Based on Dye Sensitization for Electricity and Fuel Production

Authors

  • Nick Vlachopoulos Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, School of Basic Sciences, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne
  • Anders Hagfeldt Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, School of Basic Sciences, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne

DOI:

https://doi.org/10.2533/chimia.2019.894

PMID:

31753070

Keywords:

Dye-sensitized, Mesoporous, Nanostructured, Photoelectrochemistry, Solar cell

Abstract

Dye-sensitized semiconductor oxide photoelectrodes in which light is absorbed by a monomolecular layer of dye chemisorbed on a porous oxide substrate have attracted considerable interest in the last 35 years, mainly for the conversion of sunlight to electricity, in dye-sensitized solar cells (DSSCs) with maximal efficiencies in the range 10–15%, and, most recently, as dye-sensitized photoelectrochemical cells (DSPECs) for the generation of solar fuels. In the latter direction, considerable progress has been achieved but the efficiency is notably lower than for electricity generation. In the present review, the basic physicochemical principles of the DSSC and DSPEC operation are described, several keynote results reported, and the factors limiting the performance and necessitating further research highlighted.

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Published

2019-11-01