Partialdrücke verdünnter Lösungen von Tetrahydrofuran in Äthylbenzol, 1,3-Diphenylbutan und 1,3,5-Triphenylhexan

Authors

  • R. Signer Institut für Organische Chemie der Universität Bern
  • H. Arm Institut für Organische Chemie der Universität Bern
  • B. Schnyder Institut für Organische Chemie der Universität Bern

DOI:

https://doi.org/10.2533/chimia.1967.94

Abstract

The vapor pressures of mixtures of tetrahydrofuran (THF) in ethylbenzene (AB), 1,3-diphenylbutane (DB) and 1,3,5-tri- phenylhexane (TH) as oligomers of styrene were measured in the region of Henry's law at 25 °C. The activity coefficients of THF at infinite dilution are 0.89 in AB, 0.77 in DB and 0.63 in TH. The expression dpTHF/d(nTHF/nM) (pTHF : partial pressure of THF, nTHF: moles of THF, nM moles of the monomer -CHC6H5CH2-) gives 136 in AB, 234 in DB and 297 in TH. This expression seems to reach a limiting value at still higher chain lengths of the hydrocarbons.

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Published

1967-02-28

Issue

Vol. 21 No. 2 (1967): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1967 R. Signer

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
R. Signer, H. Arm, B. Schnyder, Chimia 1967, 21, 94, DOI: 10.2533/chimia.1967.94.