Neuere Ergebnisse des photolytischen Abbaus von O-Acetyl-jervin: Struktur und Photoreaktionen der stickstofffreien Hauptprodukte

Authors

  • G. Bozzato Organisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • K. Schaffner Organisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • O. Jeger Organisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich

DOI:

https://doi.org/10.2533/chimia.1966.114

Abstract

On irradiation in dioxane with light of wavelength 253,7 nm O-acetyljervine (1) is subjected to several parallel fragmentation reactions whereas its N-acetyl derivative (2) remains photostable under the same conditions. From the mixture of basic and neutral products resulting from 1 the three major components 3, 4, and 5 have been isolated. 4 and 5 undergo further photolytically induced changes, i.e. decarbonylation to 6, and – in moist dioxane – hydrolytic cleavage to 7, respectively.

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Published

1966-04-30

Issue

Vol. 20 No. 4 (1966): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1966 G. Bozzato

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
G. Bozzato, K. Schaffner, O. Jeger, Chimia 1966, 20, 114, DOI: 10.2533/chimia.1966.114.