Untersuchungen zur Photochemie von 2-Methylindazol

Authors

  • J.P. Dubois Physikalisch-Chemisches Institut der Universität Zürich
  • H. Labhart Physikalisch-Chemisches Institut der Universität Zürich

DOI:

https://doi.org/10.2533/chimia.1969.109

Abstract

The photochemical isomerization of 2-methylindazole to 1-methylbenzimidazole is investigated with respect to the dependence of the quantum yield from wavelength of excitation, solvent, temperature and concentration. Theoretical considerations based on the change of bond orders upon excitation lead us to the assumption that the reaction starts from the lowest excited singlet-state. This is compatible with the results of experiments using sensitizers and quenchers.

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Published

1969-03-31

Issue

Section

Kurze Mitteilungen

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