Reaktivität von Koordinationsverbindungen XIX : Kinetik der Dissoziation des μ-Disauerstoff-μ-hydroxo-bis(triäthylentetramin)-dikobalt(II)-lons

Authors

  • S. Fallab Institut für Anorganische Chemie der Universität Basel

DOI:

https://doi.org/10.2533/chimia.1969.177

Abstract

The kinetics of the dissociation of a binuclear chelate of triethylenetetramine-cobalt(II)-ion with O2 and OH- as bridging ligands have been studied. In contrast to similar systems the rate of dissociation in weakly acidic solution was found to be proportional to [H+]. This suggests a mechanism in which protonation of the OH- bridge precedes the first dissociation step.

Downloads

Published

1969-05-31

Issue

Vol. 23 No. 5 (1969): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1969 S. Fallab

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
S. Fallab, Chimia 1969, 23, 177, DOI: 10.2533/chimia.1969.177.