Konstitution und Mechanismus bei der Chemilumineszenz zyklischer Diacylhydrazide

Abstract

Constitution and Mechanism in the Chemiluminescence of Cyclic Diacyl Hydrazides. After a short introduction into the principles of luminescence, especially of chemiluminescence and bioluminescence a survey is given on substituent effects concerning fluorescence and chemiluminescence of cyclic diacyl hydrazides of the luminol type [3-(2-dialkylamino-vinyl)-phthalhydrazides, 4'-amino-biphenyl-2,3-dicarboxylic hydrazides, 4'-amino-stilbene-2.3-dicarboxylic hydrazides and amino-naphthalene-1.2-dicarboxylic hydrazides)]. The chemiluminescence behavior of certain diazaquinones, e.g. 1,4-dihydro-naphtho-(2.3 g) phthalazindione (1.4), is regarded as evidence for the role of diazaquinones as key intermediates in the luminol type chemiluminescence.