Photo-Electron Spectrometry of Inorganic Solids

Authors

  • Christian Klixbüll Jørgensen Département de Chimie Physique, Université de Genève, 1211 Geneva 4

DOI:

https://doi.org/10.2533/chimia.1971.213

Abstract

The highly different probability of ionization of each shell of a given element by X-ray photons is discussed. The chemical shift of ionization energies I indicates differing Hartree potential. The multiple I of an inner shell in systems having positive spin quantum number S are studied in 11 high-spin nickel(II) compounds. The choice of scotch tape as internal standard and the Madelung potential in almost ionic compounds are treated, as well as the relation between optical electronegativities and I of valence electrons.

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Published

1971-07-31