Reduktive Alkylierungen von Acenaphthylen und Synthese von Acephenanthrylen

Authors

  • Gerd Neumann Institut für Organische Chemie Johannes-Gutenberg-Universität Mainz Postfach 3980, D-6500 Mainz 1 (Bundesrepublik Deutschland)
  • Klaus Müllen Institut für Organische Chemie Johannes-Gutenberg-Universität Mainz Postfach 3980, D-6500 Mainz 1 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1985.275

Abstract

The as yet unknown reductive alkylation of acenaphthylene with 1,n-dihalogenoalkanes is investigated. The techniques applied are the direct spectroscopic characterization of the ionic intermediates and the systematic variation of those reaction conditions which are relevant for the ion pair structures. By controlling the regioselectivity as well as the formation of cyclized/non-cyclized and monomeric/polymeric products one can substantially improve on the synthesis of several acenaphthylene derivatives.

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Published

1985-09-30

Issue

Vol. 39 No. 9 (1985): Forschung/Research

Section

Articles

License

Copyright (c) 1985 Gerd Neumann

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
G. Neumann, K. Müllen, Chimia 1985, 39, 275, DOI: 10.2533/chimia.1985.275.