Spectra of Zirconium Barium Fluoride Glass Containing Octahedrally Coordinated Chromium(III) and Nickel(II), or Mixtures of Manganese(II) and Neodymium(III)

Authors

  • Renata Reisfeld Department of Inorganic Chemistry Hebrew University 91904 Jerusalem (Israel)
  • Marek Eyal Department of Inorganic Chemistry Hebrew University 91904 Jerusalem (Israel)
  • Christian K. Jørgensen Département de Chimie minérale, analytique et appliquée, Université de Genève, Quai Ernest Ansermet 30, CH-1211 Genève 4
  • Arthur H. Guenther AFWL/CCN Kirtland, NM 87117 (USA)
  • Bernard Bendow B. D.M. Corporation 1801 Randolph Rd., SE Albuquerque, NM 87106 (USA)

DOI:

https://doi.org/10.2533/chimia.1986.403

Abstract

The absorption spectra of chromium(III) and nickel(II) on octahedral sites in a zirconium barium fluoride glass are analyzed, and compared with vitreous and crystalline mixed oxides, suggesting slightly longer Cr–F and Ni–F distances than in crystalline fluorides. Luminescence and energy transfer between manganese(II) and neodymium(III) in ZBLA glass are studied, indicating the potential for new laser materials.

Downloads

Published

1986-11-30

Issue

Vol. 40 No. 11 (1986): Forschung/Research

Section

Articles

License

Copyright (c) 1986 Renata Reisfeld

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
R. Reisfeld, M. Eyal, C. K. Jørgensen, A. H. Guenther, B. Bendow, Chimia 1986, 40, 403, DOI: 10.2533/chimia.1986.403.