Correlation of Linestrength and Linewidth in Highly-Resolved Infrared Spectroscopy

Authors

  • Gion Calzaferri Institut für Anorganische, Analytische und Physikalische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern
  • Konrad Hädener Institut für Anorganische, Analytische und Physikalische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern

DOI:

https://doi.org/10.2533/chimia.1987.119

Abstract

Rotational-vibrational spectra found in even excellent textbooks show a wrong ratio for the H35Cl/H37Cl rotational-vibrational lines. Distortion is a common problem encountered when spectral resolution is insufficient to measure the true shape of a line. Unfortunately deconvolution with the apparatus function is not always possible. In this paper the correlation of the Lorentz linewidth and linestrength in case of a Voigt profile is studied and some consequences are explained.

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Published

1987-04-30

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