Catalysis of the Copolymerization of Olefins with Carbon Monoxide: Regio- and Stereochemical Control
Keywords:Carbonylation, Cationic palladium(ii) complexes, Microstructures, Poly[olefin-alt-co], Terpolymers
AbstractLigand modification of palladium-based catalytic systems for the strictly alternating copolymerization reaction of olefin with carbon monoxide enables us to influence the stereo- and regiochemistry of the olefin insertion during the growth of the macromolecular chain. An overview of the author's research on the catalyst-based control of the macromolecular architecture and on the factors that are involved in that control is presented.
How to Cite
G. Consiglio, Chimia 2001, 55, 104, DOI: 10.2533/chimia.2001.104.
Copyright (c) 2001 Swiss Chemical Society
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