Preparation of Novel Enantiopure Ferrocenyl-Based Ligands for Asymmetric Catalysis
Keywords:Asymmetric catalysis, Ferrocenes, Phosphines
AbstractNovel enantiopure ferrocene-based aminophosphine and diphosphine ligands for asymmetric catalysts have been developed. In all cases a highly flexible synthetic approach allowed access to ligands with different ferrocenyl backbones and with a variety of functional group patterns. Procedures for the synthesis of six families of ligands with either a homo- or heteroannularly bridged ferrocene, ferrocenylmethyl, biferrocene, biferroceno-azepine or ferrocenyl-aryl framework are described in detail.
How to Cite
T. Sturm, L. Xiao, W. Weissensteiner, Chimia 2001, 55, 688, DOI: 10.2533/chimia.2001.688.
Copyright (c) 2001 Swiss Chemical Society
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