Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control
Keywords:Photochemistry, Spin, Cycloaddition, Selectivity, Magnetic Isotope Effect
Spin chemistry involving small organic molecules without heavy atoms is highly sensitive to spin-orbit-coupling (SOC) modulating biradical conformation as well as hyperfine coupling (HFC) modulating magnetic isotope interactions. Several easily available reaction properties such as chemo-, regio-, and diastereoselectivity as well as quantum yields serve as analytical tools to follow intersystem crossing dynamics and allows titrating spin selectivities.
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Copyright (c) 2021 Axel Griesbeck, Seyma Bozkus
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