Die Radiolyse von Benzol-Brombenzol-Gemischen

Authors

  • Renato Siegrist Institut de chimie physique de l'ÉPUL, Avenue des Bains 31, 1007 Lausanne
  • Tino Gäumann Institut de chimie physique de l'ÉPUL, Avenue des Bains 31, 1007 Lausanne

DOI:

https://doi.org/10.2533/chimia.1968.480

Abstract

The γ-irradiation of solutions of bromobenzene in benzene gives rise to formation of biphenyl in a yield of 70% related to the diminution of bromobenzene. The postulated reaction scheme allows to calculate both the G-value of the diminution of bromobenzene and the concentration of biphenyl, as functions of the dose. In the presence of additives one is able to calculate two quantities: the relative quenching of the additive, compared to bromobenzene and the relative reactivity of the addition reaction of phenylradicals, compared to benzene.

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Published

1968-12-31

Issue

Vol. 22 No. 12 (1968): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1968 Renato Siegrist

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
R. Siegrist, T. Gäumann, Chimia 1968, 22, 480, DOI: 10.2533/chimia.1968.480.