Synthese und Eigenschaften von Tris(trifluormethylsulfonyl)amin

Authors

  • Alois Haas Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland)
  • Christiane Klare Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1986.100

Abstract

Tris(trifluoromethylthio)amine dissolved in pentane is oxidized by sodium hypochlorite at 0°C (3.5 h) to (CF3SO2)3N. Similarly the known (CF3SO2)2NNa is prepared from (CF3S)2NH. Actually (CF3SO2)3N is the first tertiary sulfonamide at all.

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Published

1986-03-31