Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine

Authors

  • David J. Brauer Fachbereich 9, Anorganische Chemie, Universität/Gesamthochschule, D-5600 Wuppertal 1
  • Alois Haas Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland)
  • Keith E. Peterman York College of Pennsylvania, York, PA 17405 (USA)
  • Matthias Rieland Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1986.99

Abstract

Condensation of (CF3)2C=NLi with Cl3S3N3 in boiling CCl4 gives presumably the intermediate (CF3)2C=N–SN, which forms with excess (CF3)2C=NLi in the presence of moisture by a [2 + 4]-cycloaddition the isolated thiatriazine. A X-ray structure determination of the new compound as well as IR, NMR, and mass spectra are provided.

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Published

1986-03-31

Issue

Vol. 40 No. 3 (1986): Forschung/Research

Section

Articles

License

Copyright (c) 1986 David J. Brauer

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
D. J. Brauer, A. Haas, K. E. Peterman, M. Rieland, Chimia 1986, 40, 99, DOI: 10.2533/chimia.1986.99.