Lyotrop flüssigkristalline Benzolhexamin-Derivate

Authors

  • Bernd Kohne Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Klaus Praefcke Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Thomas Derz Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Heinz Hoffmann Physikalische Chemie I, Universität Bayreuth, Postfach 3008, D-8580 Bayreuth (Bundesrepublik Deutschland)
  • Barbara Schwander Institut für Organische Chemie, C 3 Technische Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12

DOI:

https://doi.org/10.2533/chimia.1986.171

Abstract

Preliminary results of investigations on hexa-amides of benzenehexamine demonstrate that these disc-shaped compounds - as such already known since 1937 - exhibit very interesting lyotropic liquid crystalline properties in various lipophilic solvents. At lower concentrations (e.g. about 20 wt.%) a nematic phase with an extraordinary wide range of stability (at least 65 °C!) has been found, whereas at higher concentrations a second mesophase exists with hexagonal structure.

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Published

1986-05-31

How to Cite

[1]
B. Kohne, K. Praefcke, T. Derz, H. Hoffmann, B. Schwander, Chimia 1986, 40, 171, DOI: 10.2533/chimia.1986.171.