Hydroformylation of Vinylferrocene with Rhodium and Platinum Catalysts

Authors

  • László Kollár Technisch-chemisches Laboratorium, Eidgenössische Technische Hochschule Zürich, ETH-Zentrum, Universitätstrasse 6, CH-8092 Zürich
  • Barbara Floris Centro C.N.R. dei Meccanismi di Reazione, Instituto di Chimica Organica, Università di Roma, I-00185 Roma
  • Piero Pino Technisch-chemisches Laboratorium, Eidgenössische Technische Hochschule Zürich, ETH-Zentrum, Universitätstrasse 6, CH-8092 Zürich

DOI:

https://doi.org/10.2533/chimia.1986.201

Abstract

2- and 3-ferrocenylpropionaldehydes (2 and 3) have been prepared by highly regioselective hydroformylation of vinylferrocene (1) using rhodium and platinum catalysts. In the asymmetric hydroformylation with a Rh/(R,R)-DIOP catalytic system a low enantiomeric excess has been achieved.

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Published

1986-06-30

Issue

Vol. 40 No. 6 (1986): Forschung/Research

Section

Articles

License

Copyright (c) 1986 Laszlo Kollar

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
L. Kollár, B. Floris, P. Pino, Chimia 1986, 40, 201, DOI: 10.2533/chimia.1986.201.