Synthese und Luftvernetzung von Dimethylfulven-Copolymerisaten

Authors

  • Ulrich Schädeli Institut für Organische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern
  • Markus Neuenschwander Institut für Organische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern

DOI:

https://doi.org/10.2533/chimia.1986.241

Abstract

Cationic copolymerization of 6,6-dimethylfulvene (1) with styrene, ethoxyethene, and cyclopentadiene has been investigated. For the system 1 (M1)/cyclopenta-diene (M2) copolymerization-parameters r1 = 21.5 and r2 = 0.053 have been determined; this shows that 1 is very easily incorporated into the growing polymer chain. Since copolymers of 1 contain structural units of type 2, they are sensitive to air, thus forming a polymeric network.

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Published

1986-08-31

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