Mechanism of the Reaction of lron(I) Ions with Neutral 4-Octyne in the Gas Phase – Experimental Evidence for an irreversible β-Hydrogen Transfer

Authors

  • Christian Schulze Institut für Organische Chemie der Technischen Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Thomas Weiske Institut für Organische Chemie der Technischen Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12
  • Helmut Schwarz Institut für Organische Chemie der Technischen Universität Berlin Strasse des 17. Juni 135, D-1000 Berlin 12

DOI:

https://doi.org/10.2533/chimia.1986.362

Abstract

Experimental evidence is presented that β-hydrogen transfer, to generate bis-olefin Fe⊕ complexes from bare Fe⊕ and 2H-labeled 4-octynes is neither reversible nor associated with a primary kinetic isotope effect; unimolecular loss of labeled ethylene from the bis-olefin Fe⊕ complexes has, however, an isotope effect of kH/kD= 1.1 per deuterium atom.

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Published

1986-10-31

Issue

Vol. 40 No. 10 (1986): Forschung/Research

Section

Articles

License

Copyright (c) 1986 Christian Schulze

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
C. Schulze, T. Weiske, H. Schwarz, Chimia 1986, 40, 362, DOI: 10.2533/chimia.1986.362.