Synthese von (all-E,14S)-14,15-Epoxy-14,15-dihydrogeranylgeranial und 1,2-Epoxy-1,2-dihydrophytoen

Authors

  • Christoph Arm Institut für Organische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern
  • Rudolf Schwabe Institut für Organische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern
  • Hanspeter Pfander Institut für Organische Chemie Universität Bern Freiestrasse 3, CH-3012 Bern

DOI:

https://doi.org/10.2533/chimia.1986.58

Abstract

The first synthesis of the optically active geranylgeranial oxide (S)-1 starting from D-mannitol including a sulfone coupling reaction as the key step is reported. Racemic phytoene oxide 2 was synthesized for the first time by coupling racemic 1 with geranylgeranyl-Wittig salt 18.

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Published

1986-02-28

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