Synthese von bicyclischen Lactonen aus Aldehyden und 2,5-Bis(trimethylsiloxy)thiophen

Authors

  • Werner Rzehak Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität Pfaffenwaldring 55 D-7000 Stuttgart 80 (Bundesrepublik Deutschland)
  • Gerhard Simchen Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität Pfaffenwaldring 55 D-7000 Stuttgart 80 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1987.152

Abstract

By reaction of 2,5-Bis(trimethylsiloxy)thiophene (3) with aldehydes (4) in presence of trimethylsilyl trifluoromethanesulfonate (1) 3,4-disubstituted thiosuccinic anhydrides (5) were obtained. Hydrolysis of the products 5 yields the bislactones 6, 7.

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Published

1987-05-31

Issue

Vol. 41 No. 5 (1987): Forschung/Research

Section

Articles

License

Copyright (c) 1987 Werner Rzehak

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
W. Rzehak, G. Simchen, Chimia 1987, 41, 152, DOI: 10.2533/chimia.1987.152.