Transition Metal Complexes with N-Heterocyclic Vinylidene Ligands

Authors

  • Bastiaan Kooij Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland
  • Tak Hin Wong Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland
  • Kay Severin Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland

DOI:

https://doi.org/10.2533/chimia.2025.855

PMID:

41432264

Keywords:

Diazoolefin, Organometallic chemistry, Transition metals, Vinylidene ligand

Abstract

Transition metal complexes with N-heterocyclic vinylidene ligands can be obtained by combining N-heterocyclic diazoolefins with suitable metal precursors. The vinylidene ligands can act as potent C-donor ligands, allowing for the stabilization of electron-deficient and low-coordinate metal complexes.

CHIMIA Vol. 79 No. 12 (2025): New Frontiers in Organometallic Chemistry

Downloads

Published

2025-12-17

Issue

Vol. 79 No. 12 (2025): New Frontiers in Organometallic Chemistry

Section

Scientific Articles

License

Copyright (c) 2025 Bastiaan Kooij, Tak Hin Wong, Kay Severin

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
B. Kooij, T. H. Wong, K. Severin, Chimia 2025, 79, 855, DOI: 10.2533/chimia.2025.855.