1,2-Di-tert-butylmethylenphosphan und seine Addukte mit Aluminiumtrichlorid, Schwefel und Selen

Authors

  • Edgar Niecke Fakultät für Chemie der Universität Postfach 8640, Universitätsstrasse, D 4800 Bielefeld 1 (Bundesrepublik Deutschland)
  • Erhard Symalla Fakultät für Chemie der Universität Postfach 8640, Universitätsstrasse, D 4800 Bielefeld 1 (Bundesrepublik Deutschland)

DOI:

https://doi.org/10.2533/chimia.1985.320

Abstract

Synthesis and spectroscopic data of a novel phosphaalkene, R–P=CH–R (2:R = C(CH3)3), are reported. With AlCl3 this phosphaalkene reacts to the Lewis acidbase adduct 7, while with sulfur and selenium it reacts to the three-membered ring compounds 8 and 9, respectively, via a nucleophilic attack at the π-system.

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Published

1985-10-31

Issue

Vol. 39 No. 10 (1985): Forschung/Research

Section

Articles

License

Copyright (c) 1985 Edgar Niecke

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
E. Niecke, E. Symalla, Chimia 1985, 39, 320, DOI: 10.2533/chimia.1985.320.