Polycyclic Phosphiranes: Synthesis of C-Substituted BABAR-Phos Compounds
Keywords:Coordination chemistry, Phosphanes, Phosphiranes, Rhodium
AbstractBABAR-Phos is a very stable polycyclic phosphirane which is easily synthesized in few steps from dibenzosuberenone. BABAR-Phos is remarkably stable and is not oxygenated with O2 nor does it react with sulfur in boiling toluene. BABAR-Phos can be used as a ligand in homogenous catalysis. Substituents at the carbon of the PC2 heterocycle can be introduced and asymmetric BABAR-Phos were prepared. The coordination chemistry of rhodium complexes containing these as ligands was investigated.
How to Cite
F. B. Läng, H. Grützmacher, Chimia 2003, 57, 187, DOI: 10.2533/000942903777679451.
Copyright (c) 2003 Swiss Chemical Society
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