Stabilization of Molecular LiF, LiFHF, and Na2SiF6 Using Metallamacrocyclic Hosts
Keywords:Chemosensor, Fluoride, Lithium, Metallamacrocycle, Sodium, Stabilization
AbstractThe molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metalla-macrocyclic complexes of (cymene)RuII, (Cp*)RhIII and (Cp*)IrIII as specific receptors. The host–guest complexes were characterized by NMR spectroscopy and single crystal X-ray diffraction. Based on these results, a highly selective chemosensor for fluoride anions has been developed.
How to Cite
M.-L. Lehaire, K. Severin, Chimia 2003, 57, 190, DOI: 10.2533/000942903777679550.
Copyright (c) 2003 Swiss Chemical Society
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.