Mn⊕-Induced Loss of Ethylene from Gaseous 4-Octyne

Authors

  • Christian Schulze Institut für Organische Chemie der Technischen Universität Berlin Strassedes 17. Juni 135, D-1000 Berlin 12
  • Helmut Schwarz Institut für Organische Chemie der Technischen Universität Berlin Strassedes 17. Juni 135, D-1000 Berlin 12

DOI:

https://doi.org/10.2533/chimia.1987.245

Abstract

The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discussed, and brief mentioning is also made on the propene loss which is unique to the [Mn(4-octyne)]⊕ complex.

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Published

1987-08-31

Issue

Vol. 41 No. 7-8 (1987): Forschung/Research

Section

Articles

License

Copyright (c) 1987 Christian Schulze

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
C. Schulze, H. Schwarz, Chimia 1987, 41, 245, DOI: 10.2533/chimia.1987.245.